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991.
M. Sassetti F. Napoli B. Kramer 《The European Physical Journal B - Condensed Matter and Complex Systems》1999,11(4):643-654
Using the bosonization technique, a theory for the collective excitations of the interacting electrons in quantum wires with
two subbands occupied is developed. The dispersion relations for the inter-subband charge and spin density excitations are
determined. The results are used to interpret the features observed in recent measurements of the Raman spectra of AlGaAs/GaAs
quantum wires, particularly for photon energies near band gap resonance. It is shown that peaks previously identified as “single
particle excitations” are signatures of higher order collective spin density excitations. Predictions about the observability
of the interband modes are made.
Received 8 February 1999 相似文献
992.
J.M. Hughes E.I. von Nagy-Felsobuki 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》1999,6(2):185-192
The electronic structure and molecular properties of helides of the form (where , Al-Ar and ) were studied using the CCSD(T) method in conjunction with the series of correlation-consistent basis sets. The highest level
of theory employed, the CCSD(T)-FC/cc-pVQZ model, was used to elucidate trends in bond lengths, dissociation energies and harmonic frequencies. The more highly
charged species were found to have shorter bond lengths than the singly charged species. The ground states of the helide cations
were often those with longer bond lengths when compared with the excited state ions.
Received: 11 May 1998 / Received in final form: 2 September 1998 相似文献
993.
Y. Zhang J. Li H. Xu H. Hou M. Nishiura T. Imamoto 《Journal of Molecular Structure》1999,510(1-3):191-196
Synthesis, structure, spectroscopy and thermal properties of complex [Co(NCS)2(hmt)2(H2O)2][Co(NCS)2(H2O)4] (H2O) (I), assembled by hexamethylenetetramine and octahedral Co(II) metal ions, are reported. Crystal data for I: Fw 387.34, a=9.020(8), b=12.887(9), c=7.95(1) Å, =96.73(4), β=115.36(5), γ=94.16(4)°, V=820(1) Å3, Z=2, space group=P−1, T=173 K, λ(Mo-K)=0.71070 Å, ρcalc=1.718567 g cm−3, μ=17.44 cm−1, R=0.088, Rw=0.148. An interesting two-dimensional network is assembled via hydrogen bonds through coordinated and free water molecules. The d–d transition energy levels of Co(II) ion are determined by UV–vis spectroscopy and calculated by ligand field theory. The calculated results agree well with experiment ones. 相似文献
994.
我们用PECVD(等离子激活化学气相沉积)方法制备SnO2薄膜。透射电镜表明400℃以下是非晶状态,扫描电镜测试表明颗粒度为30nm,SnO2薄膜的紫外可见反射吸收光谱中,沉积在石英上的SnO2薄膜出现价带到导带本征吸收带,可计算出非晶SnO2薄膜禁带宽为3.54eV,SnO2薄膜红外光谱研究表明:SnO2非晶薄膜随着加热温度升高,有序化程度升高,在300℃明显出现572cm-1的SnO2骨架振动带。经300℃老化样品只对醇敏感。为制备好的气敏材料提供理论基础。 相似文献
995.
本文就近场扫描光学显微图象及光谱这一新技术的原理,主要仪器装置及其在分析化学中的应用进行了评述,目前,这一技术已被应用于室温及大气环境中的单分子检测,显示了该技术在微区痕量分析中广阔的应用前景。 相似文献
996.
酰胺型双冠醚的振动光谱分析 总被引:4,自引:1,他引:3
对邻苯-二(氧乙酰胺-4'-本并-15-冠-5)、间苯-二(氧乙酰胺-4'-苯并-15-冠-5)、对苯-二(氧乙酰胶-4'-苯并-15-冠-5)三种酰胺型双冠醚和苯并15-冠-5的喇曼光谱及红外光谱进行了测定和归属分析,并与15-冠-5的喇曼及红外光谱进行了比较研究. 相似文献
997.
氟、氯和甲基取代丁二酰亚胺的结构、红外光谱和热力学性质的密度泛函理论研究 总被引:2,自引:0,他引:2
用密度泛函理论(DFT)的B3LYP方法(6-31G*基组),计算研究了丁二酰亚胺(SIM)的氟、氯和甲基取代物(SIMF,SIMCl和SIMMe)的几何构型、电子结构、红外光谱和热力学性质,讨论了取代基效应.结果表明,SIMF和SIMCl均为平面构型,SIMMe接近平面构型.羰基伸缩振动频率(νC=O)均分裂为两个谱带,低频带出现在1734~1771cm-1,高频带出现在1792~1822cm-1,且前者强于后者.与SIM相比,吸电子基(F和Cl)使νC=O和偶极矩增大,推电子基(CH3)的影响正相反.由校正频率计算了298~800K温度范围的热力学性质熵(S°)和热容(Cp°). 相似文献
998.
This review describes the historically important routes to fluorovinyl organometallic species of the type M-(CX=CX2), where M is a main-group or transition-metal element and one, or more, of the substituent atoms, X, is fluorine, the others being either other halogens, or hydrogen. A number of newer synthetic methods are described which have resulted in the preparation of a wider range of examples of such compounds. The structure, spectrocopy, properties, reactivity and future prospects for this class of compounds are described. 相似文献
999.
The perylene iodine system was prepared by a vapour-phase reaction without the use of solvents. Compositions between peryleneI2 and peryleneI6 were synthesized and studied by gravimetric analysis, infrared spectroscopy, X-ray diffraction and temperature-dependent resistivity measurements. Infrared spectra in the region 400–4000 cm−1 taken after different amounts of iodine were removed from the sample are distinct from perylene with new absorption lines at 1551 and 1302 cm−1 and shifts of some perylene frequencies. Powder X-ray diffraction measurements indicate that the lattice is monoclinic with parameters a=11.65 Å, b=10.85 Å, c=10.1 Å, β=100.5°. The (1 0 0) reflection, which is forbidden in the space group of perylene, is observed from the compound. The material is electrically conductive and obeys Ohm's law at high temperatures. At low temperatures and high currents, nonlinear effects are observed. The conductivity of the material increases to 1.0 (Ω cm)−1 at room temperature as the iodine content increases to a composition of peryleneI6. The resistivity obeys an exponential temperature dependence. 相似文献
1000.
首次报告在A3M2Ge3O12∶Cr(A=Cd2+,Ca2+;M=Al3+,Ga3+,Sc3+)锗酸盐石榴石体系中,Cr3+离子室温下的红—近红外(R—NIR)宽发射带光谱性质。随位于八面体格位上的Al3+→Ga3+→Sc3+和十二面体格位上的Cd2+→Ca2+组成顺序变化,室温下,Cr3+离子的4T2→4A2能级跃迁的R-NIR宽发射带,发射峰及光谱的长波和短波边逐渐向低能长波边移动。这是由于晶场强度减弱,阳离子的离子半径增大的结果。在镉(钙)铝和镉(钙)镓锗酸盐体系中,少量Sc3+取代八面体上的Al3+和Ga3+时,可使Cr3+的R-NIR荧光发射强度增强。 相似文献